Pre-Grant Publication Number: 20100280242
Filing Date: May 04, 2009Priority Date: May 04, 2008
Inventors: James L. Hedrick, Alshakim Nelson, Daniel P. Sanders
Assignee(s): International Business Machines Corporation
Current U.S. Classification: 544, 544/097000, 549, 549/228000
View Prior Art for Claim 00019
The method of Claim 18, wherein the cyclic monomer has the general structure (14):wherein Y independently represents O, S, NH or NR″; X′ represents O, S, NH, or NR″; each R′ independently represents a hydrogen, a halide, an alkyl group comprising 1 to 20 carbons, an ester group comprising 1 to 20 carbons, an amide groups comprising 1 to 20 carbons, an aryl group comprising 1 to 20 carbons, or an alkoxy group comprising 1 to 20 carbons; each R″ in Y and X′ independently represents an alkyl group comprising 1 to 20 carbons or an aryl group comprising 1 to 20 carbons; R′″ represents an alkyl group comprising 1 to 20 carbons, or an aryl group comprising 1 to 20 carbons; and z is 0 or 1.
Submitted by: Shaojun YaoLast updated: over 2 years ago
Patent/Application # 4644053
Description
Cyclic polycarbonate (or thiol analog) oligomer mixtures are prepared by the reaction of bishaloformates or their thio analogs or mixtures thereof with dihydroxy or dimercapto compounds, with alkaili metal hydroxides and various amines. The oligomer mixtures may be converted to polycarbonates or their thiol analogs by a method which is particularly adaptable to integration with polycarbonate processing operations.
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